X-Ray Spectroscopy

Sometimes referred to simply as x-ray spectroscopy, x-ray absorption spectroscopy is an element-specific probe of the local structure of elements in a material. The species of the material is determined based on its unique local structure. An important advantage of this technique is that it can be used to directly examine a wide variety of solid and liquid samples nondestructively. This method results from the absorption of a high-energy x-ray by an atom in a sample. The absorption occurs at a defined energy corresponding to the binding energy of the electron in the material. The ejected electron interacts with the surrounding atoms to produce the spectrum. Occasionally, the electron can be excited into vacant bound electronic states near the valence band and distinct absorptions will result at these energies.

X-ray absorption spectroscopy is commonly divided into two spectral regions: the x-ray absorption near-edge structure (XANES) spectral region and the extended x-ray absorption fine structure (EXAFS) region.

XANES spectra are unique to the oxidation state and species of the element of interest. As such, they are used to determine the oxidation state and coordination environment of materials. XANES spectra are commonly compared to standards in order to determine which species are present in an unknown sample. Once species are identified, their relative abundance is quantified via linear-combination fitting (or other curve-fitting algorithms) using XANES standards to reconstruct the experimental data.

EXAFS spectra are described as a series of periodic sine waves that decay in intensity as the incident energy increases from the absorption edge. These sine waves are the result of the interaction between the elected photoelectron and the surrounding atomic environment. As such, their amplitude and phase depend on the local structure of the excited atom and can be determined by matching a theoretical spectrum to the experimental spectrum. This fitting yields diverse information, including the identity of neighboring atoms, their distance from the excited atom, the number of atoms in the shell, and the degree of disorder in the particular atomic shell (as expressed by the Debye-Waller factor). These distances and coordination numbers are diagnostic of a specific mineral or adsorbate-mineral interaction. Consequently, the data is used to identify and quantify major mineral phases, adsorption complexes, and crystallinity. Linear combination of EXAFS spectra utilizing standards is also commonly used in quantization for samples containing numerous species, as it is difficult in practice to separate many species into their component shells.

PI’s Picks

These soft x-ray detection systems are excellent for x-ray absorption spectroscopy:

PIXIS-XO and PyLoN-XO CCD cameras from PI provide 16-bit digitization, excellent resolution for spectral analysis, and ultra-high-vacuum compatibility.

Another option, our uniquely designed PI-MTE, delivers reliable, deep-cooled CCD performance even when the compact camera is positioned on a movable arm in a high-vacuum environment.

Each of these high-sensitivity, wide-dynamic-range cameras utilizes a special back-illuminated CCD without antireflective coating for direct soft x-ray and EUV imaging.

X-ray spectroscopy
Image courtesy of Prof. Jens Biegert and Stephan Teichmann, The Institute of Photonic Science, Attoscience and Ultrafast Optics, Barcelona, Spain.

Example of X-ray spectroscopy experimental set-up

xray spectroscopy experimental setup



X-Ray Camera Brochure
Comprehensive information on direct and indirect X-ray detection technologies from Princeton Instruments. Includes related application and technical notes.

LightField <br> 科学成像及光谱分析软件



PyLoN <br> 成像型与光谱型相机



PIXIS-XO <br> 软X射线相机



PI-MTE<br>  真空内相机


最小巧,真空兼容,直接探测型X射线相机,探测能量从< 30 eV ~ 20 KeV

TriVista <br> 三级联光谱仪


TriVista光谱仪提供行业内最优秀的性能和灵活性; 是您真正的顶级科研工具。


特色产品 X-Ray Spectroscopy

PI-MTE<br>  真空内相机


最小巧,真空兼容,直接探测型X射线相机,探测能量从< 30 eV ~ 20 KeV